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Enantioselective Metal/Organo-Catalyzed Aerobic Oxidative sp3 C–H Olefination of Tertiary Amines Using Molecular Oxygen as the Sole Oxidant

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enantioselective_Metal_Organo_Catalyzed_Aerobic_Oxidative_sp_sup_3_sup_C_H_Olefination_of_Tertiary_Amines_Using_Molecular_Oxygen_as_the_Sole_Oxidant/2500921
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An organocatalysis/copper-catalyzed asymmetric oxidative sp3 C–H olefination reaction of tertiary amines with olefins using molecular oxygen as the sole oxidant under mild conditions was realized for the first time. This novel strategy provides an efficient and environmentally friendly way to access diversify optically active C1-alkene tetrahydroisoquinoline derivatives.
创建时间:
2016-02-20
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