Reductive Coupling of Azides Mediated by an Iron(II) Bis(alkoxide) Complex
收藏Figshare2016-02-18 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Reductive_Coupling_of_Azides_Mediated_by_an_Iron_II_Bis_alkoxide_Complex/2360743
下载链接
链接失效反馈官方服务：
资源简介：
The iron(III) hexazene complex (RO)2Fe(μ-κ2:κ2-AdN6Ad)Fe(OR)2 (3) was synthesized via reductive coupling of 1-azidoadamantane at the iron(II) bis(alkoxide) complex Fe(OR)2(THF)2 (2). The X-ray crystal structure depicts electron delocalization within the hexazene moiety. Density functional theory studies propose the formation of an iron azide dimer on the route to hexazene, in which each azide is monoreduced and the iron centers are oxidized to the 3+ oxidation state.
创建时间：
2016-02-18
