Diels-Alder Cycloaddition Polymerization for Porous Polyphenylenes with Exceptional Gas Uptake Properties
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We report the synthesis of two-dimensional and three-dimensional porous polyphenylenes (2D/3D-pPPs) via the Diels-Alder cycloaddition polymerization reaction. The resulting 2D and 3D-pPPs showed surface areas up to 1553 m2 g-1, pore volumes of 1.45 cm3 g-1 and very high H2 uptake capacities of 7.4 and 7.1 wt.% at 77K, respectively, along with a competitive high-pressure CO2 and CH4 uptake performance.
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Zenodo创建时间：
2024-02-08
