Activation-Enabled Syntheses of Functionalized Pillar[5]arene Derivatives
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https://figshare.com/articles/dataset/Activation_Enabled_Syntheses_of_Functionalized_Pillar_5_arene_Derivatives/2153500
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资源简介:
A series of regioselective
di- and trifunctionalized pillar[5]arene
derivatives have been synthesized by a deprotection-followed-by-activation
strategy, and their constitutions have been established as a result
of having access to their solid-state structures. De-O-methylation occurs in a stepwise manner at lower temperatures under
kinetic control, affording the desired oligo-substituted pillar[5]arene
derivatives. In addition, the regioisomers of these derivatives can
be isolated by installing triflate groups on the free hydroxyl groups.
创建时间:
2016-02-13



