Isostructural Mercury Coordination Polymers with Amide Junction: Interplay of Coordination and π–π Stacking
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https://figshare.com/articles/dataset/Isostructural_Mercury_Coordination_Polymers_with_Amide_Junction_Interplay_of_Coordination_and__Stacking/2481433
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资源简介：
Two coordination polymers [Hg2Cl4L·2(DMF)]n, 1, and [Hg2Br4L·2(DMF)]n, 2, where L is
the N,N′-(1,2-diphenylethane-1,2-diyl)diisonicotinamide
ligand, have been synthesized and characterized. X-ray single crystal
diffraction reveals that both coordination polymers are isostructural
and that mercury adopts square based pyramid coordination geometry.
Our results show that interplay between the coordination of the carbonyl
group and π···π interaction of adjacent
pyridine rings leads to the formation of 2D structures.
创建时间：
2016-02-20
