Novel Isopolyoxotungstate [H2W11O38]8– Based Metal Organic Framework: As Lewis Acid Catalyst for Cyanosilylation of Aromatic Aldehydes

A novel polyoxometalate-based metal organic framework (POMOF) constructed from isolated isopolyoxotungstate [H2W11O38]8– cluster, {[Cu2(bpy)­(H2O)5.5]2[H2W11O38]·3H2O·0.5CH3CN} (1, where bpy = 4,4′-bpydine), has been synthesized under solvothermal conditions and charaterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction. In 1, {W11} clusters are alternately linked by two [Cu(2)­(H2O)1.5(Ot)3(N)]2+ cations in an unexpected end-to-end fashion leading to a one-dimensional (1D) chain. Adjacent 1D chains are linked through Cu(1)–bpy–Cu(2) in an opposite direction to form a two-dimensional (2D) wavelike sheet along the ab plane. These 2D sheets are further stacked in a parallel fashion giving rise to the 1D channels with copper­(II) cations aligned in the channels. The resulting POMOF acted as a Lewis acid catalyst through a heterogeneous manner to prompt cyanosilylation with excellent efficiency.