A Highly Fluorescent Bora[6]helicene Exhibiting Circularly Polarized Light Emission

Data to report https://doi.org/10.1039/D3SC05171D:Heteroatom-doped helicenes have attracted great research interest due to their inherent chirality enabling fascinating new applications. Herein we present our successful synthesis of 19c-boratribenzo[bc,ef,hi][6]helicene, the hitherto longest and first configurationally stable pristine bora[n]helicene. It displays intense orange fluorescence and circularly polarized light (CPL) emission with a high quantum yield of up to 84%. X-ray single crystal analysis reveals a highly twisted, helical shape and intriguing intermolecular stacking. Complexation with a size-complemental aza[4]helicene yielded an unprecedented hetero-chiral π–π-stacked helicene dimer.