The Quest for Exotic Oxidation States in Main-Group Cations and Transition-Metal Fluorides
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下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-2105709227
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资源简介：
The Quest for Exotic Oxidation States in Main-Group Cations and Transition-Metal Fluorides aims to synthesize and determine crystal structures of a novel oxygen cation and a novel nitrogen oxide cation, as well as the unprecedented high-oxidation-state transition metal fluorides stabilized by high pressure in a DAC. Transition-metal fluorides with new and unusual oxidation states would be synthesized by an innovative approach – laser-heating-induced decomposition of the respective fluoridometallate salts of pentafluoridoxenon(1+) cation. This proposal is composed of two parts: i) a selection of low risk targets with strong preliminary data and ii) an exploratory high-risk–high-gain proof-of-concept research, that would, even if partially successful, open a new direction and provide strong case for further investigation and beamtime proposals.
提供机构：
Jozef Stefan Institute, Extreme Conditions Chemistry Laboratory, Jamova cesta 39, 1000, Ljubljana, SI; Cardinal Stefan Wyszynski University inWarsaw, Faculty ofMathematics and Natural Sciences, ul. Wóycickiego 1/3, 01-938, Warsaw, POLAND; Institute Jozef Stefan, Jamova 39 p.p.3000, 1001, Ljubljana, SI; Jozef Stefan Institute, Extreme Conditions Chemistry Laboratory, Jamova cesta 39, 1000, Ljubljana, SLOVENIA
创建时间：
2028-01-01
