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Synthesis and Coordination Chemistry of a Photoswitchable Bis(phosphine) Ligand

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https://figshare.com/articles/dataset/Synthesis_and_Coordination_Chemistry_of_a_Photoswitchable_Bis_phosphine_Ligand/3271738
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A 1,2-dithienylethene compound bearing bis(phosphine) groups (1o) represents a new class of photoresponsive ligands where there are steric and electronic differences between two photogenerated isomers. The coordination chemistry of this ligand class is demonstrated by preparing a gold(I) complex (2o) and a phosphine selenide (3o).
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2016-05-05
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