five

Generation and Decomposition of Li/OR Phosphinidenoid Complexes

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Generation_and_Decomposition_of_Li_OR_Phosphinidenoid_Complexes/2638327
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Reaction of the P-bifunctional phosphane complex 2 with LDA and 12-crown-4 yielded complex 4, featuring the unprecedented combination of a P–H and P–O–Li unit, via an unknown decomposition pathway. Strong spectroscopic evidence for the transient Li/OC(O)CH3 phosphinidenoid complex 5 possessing a P–Li bond was obtained through reaction of 2 with LDA in the absence of 12-crown-4.
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2016-02-23
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