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Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Enantioselective_1_6_Addition_of_Arylboronic_Acids_to_Enynamides_Asymmetric_Synthesis_of_Axially_Chiral_Allenylsilanes/2728111
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资源简介:
Rhodium-catalyzed asymmetric 1,6-addition of arylboronic acids to β-alkynyl acrylamides substituted with a silyl group on the alkyne terminus took place to give high yields of axially chiral allenylsilanes with 94−99% enantioselectivity, which was realized by use of a rhodium/chiral diene complex.
创建时间:
2010-09-22
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