Fast Synthesis of Hydrazine and Azo Derivatives by Oxidation of Rare-Earth-Metal−Nitrogen Bonds
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Fast_Synthesis_of_Hydrazine_and_Azo_Derivatives_by_Oxidation_of_Rare_Earth_Metal_Nitrogen_Bonds/2692402
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资源简介:
A novel N−N coupling reaction was developed through the oxidation of rare-earth-metal−nitrogen bonds produced by treatment of the easily available rare-earth-metal amides [(Me3Si)2N]3RE(μ-Cl)Li(THF)3 with aromatic primary or secondary amines. The reaction provides the symmetrical or unsymmetrical azo compounds and hydrazine derivatives in good to high yields within a very short time under mild conditions.
创建时间:
2016-02-23



