Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes
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https://figshare.com/articles/dataset/Mass_Spectrometric_Studies_of_Reductive_Elimination_from_Pd_IV_Complexes/2336596
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资源简介：
Reductive elimination
of ethane from the palladium(IV) complex
[PdMe3(bpy)I] (bpy = 2,2′-bipyridine) is studied
by electrospray ionization mass spectrometry. Palladium(IV) complexes
can be detected as binuclear clusters [Pd2Me6I(bpy)2]+ or as complexes [PdMe3(bpy)(L)]+ stabilized by an electron-donating ligand L.
Fragmentation of all palladium(IV) complexes is dominated by elimination
of ethane which corresponds to the reductive elimination coupling
of the methyl groups. The associated energy demands for different
complexes reveal that the mononuclear complexes with poorly electron-donating
ligands provide the fastest reaction.
创建时间：
2016-02-18
