Design, Synthesis, Characterization, and Catalytic Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site Vanadyl(monocatecholate) Moieties
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https://figshare.com/articles/dataset/Design_Synthesis_Characterization_and_Catalytic_Properties_of_a_Large_Pore_Metal_Organic_Framework_Possessing_Single_Site_Vanadyl_monocatecholate_Moieties/2389387
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资源简介：
Through a combination of protecting
groups, postsynthesis deprotection,
and postsynthesis metallation, a homogeneously inaccessible, single-site
vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl
struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF,
which has large pores, exhibits catalytic activity in the benzylic
oxidation of tetralin in the presence of tert-butylhydroperoxide.
创建时间：
2016-02-19
