Iron(III)-Mediated Radical Nitration of Bisarylsulfonyl Hydrazones: Synthesis of Bisarylnitromethyl Sulfones
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https://figshare.com/articles/dataset/Iron_III_Mediated_Radical_Nitration_of_Bisarylsulfonyl_Hydrazones_Synthesis_of_Bisarylnitromethyl_Sulfones/2153170
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资源简介：
Iron(III)-mediated radical nitration
of bisarylsulfonyl hydrazones
is described. In this protocol, the nontoxic and inexpensive Fe(NO3)3·9H2O plays a dual role as catalyst
as well as nitro source. The mild conditions, broad substrate scope,
and the functional group compatibility are the significant features.
The reaction pathway has been demonstrated using DFT calculations,
and the products can be subsequently converted into oximes using SnCl2·2H2O in high yields.
创建时间：
2016-02-13
