Base-Promoted Decarboxylative Azo-Coupling: Construction of Unsymmetrical Azocarboranes
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https://figshare.com/articles/dataset/Base-Promoted_Decarboxylative_Azo-Coupling_Construction_of_Unsymmetrical_Azocarboranes/4602376
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资源简介：
Base-promoted decarboxylative azo
couplings of carboranyl carboxylic
acids with diazo salts have been developed to provide trans-azocarboranes in high yields (up to 94%). This approach is simple,
efficient, and compatible with various functional groups. Mechanistically,
the coupling has been proven to proceed in a nonradical pathway, which
is distinct from those classical decarboxylative couplings.
创建时间：
2017-02-01
