Base-Promoted Decarboxylative Azo-Coupling: Construction of Unsymmetrical Azocarboranes
收藏NIAID Data Ecosystem2026-03-10 收录
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资源简介：
Base-promoted decarboxylative azo couplings of carboranyl carboxylic acids with diazo salts have been developed to provide trans-azocarboranes in high yields (up to 94%). This approach is simple, efficient, and compatible with various functional groups. Mechanistically, the coupling has been proven to proceed in a nonradical pathway, which is distinct from those classical decarboxylative couplings.
创建时间：
2017-02-01
