Solvent-Controlled Switchable C–H Alkenylation of 4‑Aryl‑1<i>H</i>‑pyrrole-3-carboxylates: Application to the Total Synthesis of (±)-Rhazinilam
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A solvent-controlled switchable C–H alkenylation of 4-aryl-1H-pyrrole-3-carboxylates via a Pd(OAc)2 catalyzed oxidative Heck reaction was first realized. The corresponding C2 and C5 alkenylation products were obtained in good yields with high regioselectivities, respectively. The selective C5-alkenylation was successfully applied to the total synthesis of (±)-rhazinilam.
创建时间：
2014-09-19
