Catalytic Enantioselective Total Synthesis of Hypocrolide A
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Total_Synthesis_of_Hypocrolide_A/3823314
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资源简介：
The first and catalytic enantioselective
total synthesis of hypocrolide
A (>99% ee) in 12 steps, as well as other botryanes, is described.
The absolute configurations of these compounds have been unambiguously
confirmed or reassigned accordingly. The key reactions in this study
include an unusual rhodium-catalyzed intramolecular [4 + 2] cycloaddition
and a biomimetic oxidative [3 + 2] cycloaddition based on our revised
biogenetic pathway.
创建时间：
2016-10-03
