Asymmetric Hydrogenation via Capture of Active Intermediates Generated from Aza-Pinacol Rearrangement
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https://figshare.com/articles/dataset/Asymmetric_Hydrogenation_via_Capture_of_Active_Intermediates_Generated_from_Aza_Pinacol_Rearrangement/2235697
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资源简介：
An
efficient palladium-catalyzed asymmetric hydrogenation via capture
of an active intermediate generated in situ from acid-catalyzed aza-Pinacol
rearrangement has been successfully developed, providing efficient
access to chiral exocyclic amines with up to 98% ee. Three-, four-,
and five-membered cyclic N-sulfonyl amino alcohols
are viable substrates. This study opens a new window to the application
of asymmetric hydrogenation.
创建时间：
2016-02-16
