Enantioselective Synthesis of Chiral Oxygen-Containing Heterocycles Using Copper-Catalyzed Aryl C–O Coupling Reactions via Asymmetric Desymmetrization
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Chiral_Oxygen-Containing_Heterocycles_Using_Copper-Catalyzed_Aryl_C_O_Coupling_Reactions_via_Asymmetric_Desymmetrization/4568008
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资源简介：
An enantioselective
desymmetric aryl C–O coupling reaction
was demonstrated under the catalysis of CuI and a chiral cyclic diamine
ligand. A series of chiral oxygen-containing heterocyclic units such
as 2,3-dihydrobenzofurans, chromans, and 1,4-benzodioxanes with tertiary
or quaternary stereocarbon centers were synthesized with this method.
DFT calculations were also carried out for a better understanding
of the model for enantiocontrol.
创建时间：
2017-01-19
