Materials Data on OsClF8 by Materials Project

OsF6ClF2 is beta-prime cadmium gold structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two osmium hexafluoride molecules and two ClF2 clusters. In each ClF2 cluster, Cl is bonded in a distorted rectangular see-saw-like geometry to two equivalent F atoms. Both Cl–F bond lengths are 1.62 Å. F is bonded in a single-bond geometry to one Cl atom.OsF6ClF2 具有β'-型镉金结构，其晶体属于三斜晶系P-1空间群。该结构为零维结构，由两个六氟化锇（osmium hexafluoride）分子与两个ClF2团簇构成。在每个ClF2团簇中，Cl原子以扭曲的矩形跷跷板状几何构型与两个等价的F原子成键，二者的Cl-F键长均为1.62埃（Å）。F原子则以单键几何构型与一个Cl原子成键。