Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand
收藏NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Reactivity_of_a_Mononuclear_Iridium_I_Species_Bearing_a_Terminal_Phosphido_Fragment_Embedded_in_a_Triphosphorus_Ligand/2442424
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资源简介：
The first example of an iridium(I) species bearing a
terminal phosphido (PR2–) ligand is reported.
This stable compound shows well-behaved reactivity toward various
electrophiles, owing to its exposed phosphorus lone pair, allowing
reversible protonation, selective alkylation, isolation of a phosphidoborane
of iridium, and generation of a phosphido-bridged iridium(I)–gold(I)
dinuclear species.
创建时间：
2016-02-19
