Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand
收藏NIAID Data Ecosystem2026-03-07 收录
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The first example of an iridium(I) species bearing a terminal phosphido (PR2–) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)–gold(I) dinuclear species.
创建时间：
2016-02-19
