Dataset for: BIOCHAR IMMOBILIZES AND DEGRADES 2,4,6-TRICHLOROPHENOL IN SOILS

Soil contamination by chlorophenol compounds, such as 2,4,6-trichlorophenol (2,4,6-TCP), is of great concern because they are environmentally persistent, difficult to degrade, and can lead to cancer. Thus, means of degrading these compounds in-situ are desperately needed. Biochar was investigated as a material to sequester, reduce downward transport, and aid in soil 2,4,6-TCP degradation. In two column studies, wheat straw (Triticum aestivum L.)-derived biochar (pyrolyzed at 450 oC) application to soil (up to 5% by wt.) improved soil water and soil organic carbon (SOC) content. Biochar reduced 2,4,6-TCP downward transport, likely due to improved soil water mobility and retention allowing 2,4,6-TCP to be more easily transported and sorbed to organic functional groups on biochar, leading to enhanced degradation. The 2,4,6-TCP was rapidly degraded into a combination of benzene derivatives and low molecular weight organic compounds in the first two months following biochar application. This study provides evidence that biochars can be used to improve environmental quality by lessening the downward transport and enhancing the degradation of the organochlorine compounds such as 2,4,6-TCP.