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Materials Data on LiCN by Materials Project

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Mendeley Data2024-01-31 更新2024-06-28 收录
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https://www.osti.gov/servlets/purl/1204484/
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LiCN crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two LiCN ribbons oriented in the (1, 0, 0) direction. Li1+ is bonded in a distorted T-shaped geometry to three equivalent N3- atoms. There are one shorter (2.07 Å) and two longer (2.18 Å) Li–N bond lengths. C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.18 Å. N3- is bonded in a see-saw-like geometry to three equivalent Li1+ and one C2+ atom.
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2024-01-31
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