Olefin Oxygenation by Water on an Iridium Center
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https://figshare.com/articles/dataset/Olefin_Oxygenation_by_Water_on_an_Iridium_Center/2206900
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资源简介：
Oxygenation
of 1,5-cyclooctadiene (COD) is achieved on an iridium
center using water as a reagent. A hydrogen-bonding interaction with
an unbound nitrogen atom of the naphthyridine-based ligand architecture
promotes nucleophilic attack of water to the metal-bound COD. Irida-oxetane
and oxo-irida-allyl compounds are isolated, products which are normally
accessed from reactions with H2O2 or O2. DFT studies support a ligand-assisted water activation mechanism.
创建时间：
2016-02-15
