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Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Divalent_Dirhodium_Imido_Complexes_Formation_Structure_and_Alkyne_Cycloaddition_Reactivity/2927599 数据链接链接失效反馈

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Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity

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创建时间：

2008-07-16

有机金属催化

杂环化合物构建

Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq

Figshare2016-02-12 更新70

Knölker-Type Iron Complexes Bearing an N‑Heterocyclic Carbene Ligand: Synthesis, Characterization, and Catalytic Dehydration of Primary Amides

有机金属催化

酰胺化反应

A family of iron Knölker-type complexes bearing an N-heterocyclic carbene (NHC) ligand has been synthesized from the corresponding tricarbonyl(η4-cyclopentadienone)iron complex by reaction with the

Figshare2016-02-13 更新30

Isomeric Palladium Complexes Bearing Imidazopyridine-Based Abnormal Carbene Ligands: Synthesis, Characterization, and Catalytic Activity in Direct C–H Arylation Reaction

有机金属催化

CH活化

A series of “abnormal” NHC ligand precursors based on imidazopyridines and their corresponding NHC-palladium diiodide complexes were prepared. Our study included the first report on a palladium comple

NIAID Data Ecosystem20

Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex

有机金属催化

硼烷化合物合成

Selective B–O–Si bond formation was achieved in the reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane R3SiH in the presence of stoichiometric water and

NIAID Data Ecosystem60

Catalytic C–H Alumination of Thiophenes: DFT Predictions and Experimental Verification

C-H键活化

有机金属催化

A computational model for the palladium-catalyzed C–H functionalization of thiophenes with aluminum hydride reagents has been developed. This model predicts that metalation should occur exclusively at

NIAID Data Ecosystem30

Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity

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