High Nuclearity in Azido/Oximate Chemistry: Ni<sub>14</sub> and Ni<sub>13</sub> Clusters with <i>S</i> = 6 and 9 Ground States
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In the present work, we report a family of Ni14 and unprecedented Ni13 clusters linked by end-on azido and oximato bridges. Ferrimagnetic response gives S = 6 and 9 ground states, resulting in the largest nuclearities and spins in nickel oximato chemistry.
创建时间:
2012-05-21



