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Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes

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NIAID Data Ecosystem2026-03-11 收录
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Diphosphine-Bridged_Diruthenium_Complexes/12263438
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Treatment of a chloride-bridged tetraruthenium complex with tetramethyldiphoshine and tetraphenyldiphosphine affords a different type of diphosphine-bridged diruthenium complexes, which are further transformed into the corresponding cationic complexes by treatment with silver trifluoromethanesulfonate. Some diphosphine-bridged diruthenium complexes show a catalytic activity toward the quantitative cyclotrimerization of ethyl propiolate to two regioisomeric benzene derivatives.
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2007-07-02
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