Hybrid Metal Carbonyl−Oxide Clusters: Synthesis and Structure of [Et<sub>4</sub>N]<sub>2</sub>[(OC)<sub>5</sub>WSbW<sub>3</sub>(CO)<sub>9</sub>(μ<sub>3</sub>-OMe)<sub>2</sub>(μ<sub>3</sub>-O)WO<sub>2</sub>(OR)] (R = Me, H)
收藏NIAID Data Ecosystem2026-03-06 收录
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The novel hybrid metal carbonyl−oxide cluster [Et4N]2[(OC)5WSbW3(CO)9(μ3-OMe)2(μ3-O)WO2(OMe)] produced from W(CO)6 and NaSbO3 contains a SbW3 tetrahedron that is triply bridged by the tungsten trioxide [WO3(OMe)3]3-. The terminal methoxide is loosely coordinated and can be hydrolyzed to produce the hydroxide derivatives.
创建时间：
2016-08-26
