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Nitrile-Rich Coordination Polymer <sup>1</sup><sub>∞</sub>{[Fe(CH<sub>3</sub>CN)<sub>4</sub>(pyrazine)](ClO<sub>4</sub>)<sub>2</sub>} Exhibiting a HS ⇆ LS Transition

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NIAID Data Ecosystem2026-03-06 收录
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In a 1D network of 1∞{[Fe(CH3CN)4(pyrazine)](ClO4)2}, the presence of four neutral nitrile molecules besides the pyrazine donors in the first coordination sphere of iron(II) allows one to achieve a ligand field strength appropriate for the “spin-crossover” occurrence.

创建时间:
2010-12-20
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