Practical Synthesis of P-Stereogenic Diphosphacrowns
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https://figshare.com/articles/dataset/Practical_Synthesis_of_P_Stereogenic_Diphosphacrowns/2852530
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资源简介:
P-Stereogenic 18-diphosphacrown-6 derivatives containing a chiral bisphosphine unit were synthesized. This is the first practical method for the synthesis of optically pure diphosphacrowns. The diphosphacrowns have the structure of a chiral figure “8” with chiral heteroatoms that interact directly with guest ions and molecules. Pd(II) and Pt(II) complexes with the P-stereogenic diphosphacrowns were also synthesized and characterized.
创建时间:
2016-02-26



