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C-2/C-3 Annulation and C-2 Alkylation of Indoles with 2-Alkoxycyclopropanoate Esters
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/C-2_C-3_Annulation_and_C-2_Alkylation_of_Indoles_with_2-Alkoxycyclopropanoate_Esters/12064521
下载链接
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资源简介：
The annulation reaction between various indoles and 2-alkoxycyclopropanoate esters is reported.
Both high efficiency and complete stereochemical control were observed in some cases with this annulation
process. A single stereocenter on the cyclopropane controls the diastereoselective formation of up to four
new stereocenters. A different reaction course was observed with 3-substituted indole substrates, and an
intervening C-3 to C-2-migration process arose that gives synthetically useful C-2 alkylation indole products.
创建时间：
2020-04-02
