Two Novel 3d-4f Heterometallic Frameworks Assembled from a Flexible Bifunctional Macrocyclic Ligand
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https://figshare.com/articles/dataset/Two_Novel_3d_4f_Heterometallic_Frameworks_Assembled_from_a_Flexible_Bifunctional_Macrocyclic_Ligand/2481469
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资源简介:
Two novel 3d-4f heterometallic porous metal–organic
frameworks
with a flexible bifunctional macrocyclic ligand have been successfully
synthesized and characterized. The mononuclear [M(TETA)]2– complexes exhibiting two kinds of connection models to lanthanide
ions give rise to three-dimensional pillared-layer frameworks with
highly solvent accessible volume. Interpenetration is avoided by using
the nanosized secondary building units of transition
metal macrocyclic complex.
创建时间:
2016-02-20



