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Two Novel 3d-4f Heterometallic Frameworks Assembled from a Flexible Bifunctional Macrocyclic Ligand

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Two_Novel_3d_4f_Heterometallic_Frameworks_Assembled_from_a_Flexible_Bifunctional_Macrocyclic_Ligand/2481469
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Two novel 3d-4f heterometallic porous metal–organic frameworks with a flexible bifunctional macrocyclic ligand have been successfully synthesized and characterized. The mononuclear [M­(TETA)]2– complexes exhibiting two kinds of connection models to lanthanide ions give rise to three-dimensional pillared-layer frameworks with highly solvent accessible volume. Interpenetration is avoided by using the nanosized secondary building units of transition metal macrocyclic complex.
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2016-02-20
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