Synthesis of γ‑Lactams by Intermolecular (3 + 2) Annulation of Siloxy Alkynes and 3‑Aminooxetanes
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https://figshare.com/articles/dataset/Synthesis_of_Lactams_by_Intermolecular_3_2_Annulation_of_Siloxy_Alkynes_and_3_Aminooxetanes/28781020
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资源简介:
A silver-catalyzed intermolecular (3 + 2) annulation
of siloxy
alkynes and 3-aminooxetanes has been developed. This process provides
mild and convenient access to useful γ-butyrolactams with high
regio- and stereoselectivity. Mechanistically, intermolecular C–N
bond formation likely precedes oxetane ring opening.
创建时间:
2025-04-11



