Si−N Bond Hydrolysis Furnishes a Planar 4-Coordinate 14-Electron Ru(II) Complex with a Triplet Ground State
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https://figshare.com/articles/dataset/Si_N_Bond_Hydrolysis_Furnishes_a_Planar_4_Coordinate_14_Electron_Ru_II_Complex_with_a_Triplet_Ground_State/3071584
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资源简介：
Reaction of stoichiometric (2:1) water with [(tBu2PCH2SiMe2)2N]Ru(OSO2CF3) produces planar, 14-valence-electron
spin triplet trans-Ru(tBu2PCH2SiMe2O)2. A possible mechanism for this hydrolysis is discussed. This molecule reacts
rapidly with CO to give a monocarbonyl, then a cis-dicarbonyl. Reaction with HCCR (R = H or Ph) yields the
vinylidene (tBu2PCH2SiMe2O)2RuCCHR.
创建时间：
2016-03-01
