Single-crystal X-ray diffractometry data for a sample of NiCl₂-dppe collected on beamline I19-2 at Diamond Light Source
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Single-crystal X-ray diffractometry data for a sample of [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) (NiCl<sub>2</sub>-dppe, [(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>]NiCl<sub>2</sub>). Data collected at Diamond Light Source I19-2 on 2015-05-18, publicly available for users to test data reduction routines. Data are known to produce good merging statistics and final refinements. The sample was prepared as follows:<br> Nickel chloride (II) hexahydrate (1 g, 2 mmol) was heated under vacuum to produce anhydrous nickel chloride (II) with a visible colour change from green to yellow. The resulting solid was taken up in ethanol (5 ml) and added to 1,2-bis(dimethylphosphine)ethane (dppe) (0.837 g, 2 mmol) in ethanol (10 ml). The solution was refluxed for 3 hour after which the solvent was evaporated. The small red crystals were purified by recrystallisation in acetone (70% yield). The sample was held at an approximate temperature of 150 K and the illuminating beam had a wavelength of 0.68890 Å (17.997 keV). The detector was held at 2θ = 25° throughout. Inventory of data:<br> <strong>010_Ni_dppe_Cl_2_150K01</strong> — 130° ω scan, 0.4° images, 0.4s per image, 325 images; κ = 45°, φ = 160°.<br> <strong>010_Ni_dppe_Cl_2_150K02</strong> — 130° ω scan, 0.4° images, 0.4s per image, 325 images; κ = 45°, φ = 40°.<br> <strong>010_Ni_dppe_Cl_2_150K03</strong> — 130° ω scan, 0.4° images, 0.4s per image, 325 images; κ = 45°, φ = -80°.<br> <strong>010_Ni_dppe_Cl_2_150K04</strong> — 198° ω scan, 0.4° images, 0.4s per image, 495 images; κ = 0°, φ = -80°.
