Straightforward Assembly of the Octahydroisoquinoline Core of Morphinan Alkaloids
收藏NIAID Data Ecosystem2026-03-06 收录
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The octahydroisoquinoline core of morphinan was assembled starting from readily available arylcyclohexadienes. Three different approaches were developed, including a metal- and an acid-mediated Mannich type process and an anionic-mediated cyclization. All provided the desired motif as a single diastereomer having a C9−C13−C14 trans−cis relative configuration.
创建时间：
2010-05-21
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