Carbon−Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions
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https://figshare.com/articles/dataset/Carbon_Carbon_Bonds_of_Manganese_Half_Sandwich_Complexes_for_Electron_Reservoir_Functions/3346627
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资源简介：
Vinylidene species of the type Mn(C5H4CH3)[(H3C)2PCH2CH2P(CH3)2](CCR1R2) (R1 = R2 =
H; R1 = H, R2 = Ph) can be fully reversibly coupled to
yield the dinuclear complexes [(C5H4CH3)(dmpe)Mn⋮CC(R1)(R2)C(R1)(R2)C⋮Mn(dmpe)(C5H4CH3)][PF6]2 (R1,
R2 = H; R1 = H, R2 = Ph) by an oxidation/reduction
cycle involving formation and cleavage of a C−C σ bond.
创建时间：
2004-03-15
