Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property
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https://figshare.com/articles/dataset/Copper_Complexes_Bearing_a_Dianionic_Diborane_4_Ligand_Synthesis_and_Evaluation_of_the_Donor_Property/11833116
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资源简介：
A series of mono-
and dinuclear copper complexes 2–4 bearing a η2-dianionic diborane(4)
ligand was synthesized and characterized. The strong donating ability
of the dianionic diborane(4) ligand was evaluated by IR spectrum,
structural parameters in the crystal, XANES spectra, and DFT calculations.
The NBO calculations revealed that the π-backdonation to dianionic
diborane(4) ligand is weaker than that to the ethylene ligand due
to the dianionic charges on the boron atoms.
创建时间：
2020-02-10
