A Highly Stereoselective Metal-Free Hydrogenation of Diimines for the Synthesis of Cis-Vicinal Diamines
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https://figshare.com/articles/dataset/A_Highly_Stereoselective_Metal_Free_Hydrogenation_of_Diimines_for_the_Synthesis_of_i_Cis_i_Vicinal_Diamines/2156938
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A highly stereoselective metal-free hydrogenation of vicinal diimines has been successfully realized for the first time using 5–10 mol % of Piers’ borane as a catalyst under mild conditions, and a variety of cis-1,2-diamines were obtained in 92–99% yields. The current work provides a novel and efficient approach for the synthesis of vicinal diamines.
创建时间：
2016-02-13
