B←N Lewis Pair-Functionalized Perylenes: Tuning Optoelectronic Properties via Regioisomerization
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https://figshare.com/articles/dataset/B_N_Lewis_Pair-Functionalized_Perylenes_Tuning_Optoelectronic_Properties_via_Regioisomerization/28418143
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Herein, we report two peri-regioisomers of B←N Lewis pair-functionalized perylenes: the centrosymmetric PBNPf1 and the mirror-symmetric PBNPf2. Mirror-symmetric functionalization more effectively tunes the photoelectronic properties. The LUMO energy levels of PBNPf1 and PBNPf2 are stabilized to −3.00 eV and −3.30 eV. Additionally, the emission maxima of PBNPf1 and PBNPf2 are shifted to 574 and 628 nm, with fluorescence quantum yields of up to 96% and 87%, respectively.
创建时间：
2025-02-14
