Synthesis, Characterization, and Reactivity of a Rhenium Complex with a Corannulene-Based Ligand
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https://figshare.com/articles/dataset/Synthesis_Characterization_and_Reactivity_of_a_Rhenium_Complex_with_a_Corannulene_Based_Ligand/3360418
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资源简介：
A new rhenium carbonyl complex, exo-(η5-C20H17)Re(CO)3 (3), containing a corannulene-derived
ligand has been synthesized in 12% yield. The X-ray
structure determination of 3 shows that the rhenium
center is bound to the exo face of the bowl-shaped ligand.
The reaction of 3 with PPh3 in benzene at 70 °C produces
trans,mer-Re(H)(PPh3)2(CO)3 and C20H16 (4), a bowl-shaped dibenzofulvene type molecule. The reaction of 3
with PPh3 proceeds via an η5-η3-η1 ring slip followed by
a β-hydride elimination.
创建时间：
2016-05-07
