Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn<sub>2</sub>SnS<sub>4</sub>(N<sub>2</sub>H<sub>4</sub>)<sub>2</sub>]
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The reaction system Mn/Sn/S/hydrazine/water at ∼150 °C afforded [Mn2SnS4(N2H4)2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.
创建时间：
2009-06-01
