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Beyond the Butterfly: Sc<sub>2</sub>C<sub>2</sub>@<i>C</i><sub>2<i>v</i></sub>(9)‑C<sub>86</sub>, an Endohedral Fullerene Containing a Planar, Twisted Sc<sub>2</sub>C<sub>2</sub> Unit with Remarkable Crystalline Order in an Unprecedented Carbon Cage

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The synthesis, isolation, and characterization of a new endohedral fullerene, Sc2C88, is reported. Characterization by single crystal X-ray diffraction revealed that it is the carbide Sc2C2@C2v(9)-C86 with a planar, twisted Sc2C2 unit inside a previously unseen C2v(9)-C86 fullerene cage.

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2016-02-15
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