Stimuli-Responsive B/N Lewis Pairs Based on the Modulation of B–N Bond Strength

A series
of robust organoboranes with electronically tunable functionality
of B/N Lewis pairs has been achieved. These compounds feature a B/N-containing
core in which the interactions between the B and N atoms are modulated
as a result of the structural flexibility of the nonconjugated backbone.
Examination of the substituent effects of the Lewis base moiety reveals
that bulky or aryl substituents favor the dynamic switching of the
B–N bond in response to external stimuli, such as heat or mechanical
pressure, leading to emission color modulation. This work provides
a new, straightforward proof of concept toward new switchable materials
design based on tunable electronic interactions.