Synthesis, Crystal Structure, and Solution Behavior of a Sterically Hindered α-Metalated Phosphine-Borane
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https://figshare.com/articles/dataset/Synthesis_Crystal_Structure_and_Solution_Behavior_of_a_Sterically_Hindered_Metalated_Phosphine_Borane/3246322
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资源简介：
Treatment of the phosphine-borane adduct (Me3Si)2CHPMe2(BH3) (4) with n-BuLi in THF, followed by recrystallization from diethyl ether/methylcyclohexane, gives (THF)3Li{(Me3Si)2CPMe2(BH3)}2Li (5), which crystallizes as a contact
ion multiple ate complex. In solution 5 is subject to a dynamic
equilibrium between the ate complex and a second, possibly
monomeric species.
创建时间：
2016-05-05
