Generation and Reactivity of a New Heterocyclic Silylene, a Silaazaanthracene
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https://figshare.com/articles/dataset/Generation_and_Reactivity_of_a_New_Heterocyclic_Silylene_a_Silaazaanthracene/3763587
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资源简介：
The cyclic silylene 6, a silaazaanthracene
derivative, which possesses 14-electrons, has been generated by the reduction of 10,10-dichloro-5-methyl-5,10-dihydrophenazasiline (5) with lithium naphthalenide.
Reactions of 6 with 2,3-dimethyl-1,3-butadiene, isoprene,
and triethylvinylsilane gave the corresponding silylene-trapping products, 7, 8, and 9, in moderate yield.
Pseudoaromatic stabilization of the cyclic silylene 6 was
not observed, possibly due to the fact that the three rings
are not coplanar.
创建时间：
2016-08-26
