Crystalline Monomeric Allenyl/Propargyl Radical
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下载链接：
https://figshare.com/articles/dataset/Crystalline_Monomeric_Allenyl_Propargyl_Radical/5538007
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资源简介：
Reduction of alkynyl iminium salts
derived from cyclic (alkyl)(amino)carbenes
(CAACs) affords propargyl/allenyl radicals. Depending on the nature
of the CAAC and alkyne substituents, these radicals can irreversibly
dimerize, exist as monomers in solution but dimerize in the solid
state, or can even remain monomeric as solids. The first characterization
of an allenyl radical by single crystal X-ray crystallography is reported.
创建时间：
2017-10-25
